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27 July 2021 | Story Leonie Bolleurs | Photo UFS Photo Archive
Prof Hendrik Swart played a key role in the Department of Physics acquiring the PHI Quantes XPS system, the first in Africa and one of only 20 in the world.

The state-of-the-art equipment in the Department of Physics at the University of the Free State (UFS) differentiates this department from its competitors. Availability of the equipment makes it possible for researchers as well as students to deliver work that receives national and international recognition. 

Recently, the department acquired a PHI Quantes XPS system, the first in Africa and one of only 20 in the world. 

Creating better phosphor 

“The Quantes XPS system uses X-rays to determine the chemical composition of molecules on the surface of a sample. The system is unique in the sense that it also has an extra X-ray source that can determine the chemical state below the surface, which was not possible in the past.  This will help us to dictate the position of defects in our phosphor materials that will consequently enable us to create better phosphor for solid state lighting as well as solar cell applications,” explains Prof Hendrik Swart, Senior Professor in the Department of Physics, who also holds the SARChI Chair in Solid State Luminescent and Advanced Materials.

After he had the opportunity to observe the system in the factory in Chigasaki, Kanagawa, Japan, where he attended a conference, Prof Swart was very impressed by its performance. He discussed it with Prof Koos Terblans, Head of the department, and other colleagues, and started making plans to buy the system. 

When the department first bought the X-ray photoelectron spectroscopy (XPS) system in 2007/2008, it became the national facility on XPS measurements. Not only is this an upgrade of the XPS system bought 14 years ago, but the new system will enable the department to do more measurements. “The number of samples that we have to handle has just become too much for one system. The new system’s increased capacity for making measurements addresses this challenge and it also gives UFS scientists and postgraduate students more time to spend on fundamental measurements to develop research of a higher level,” says Prof Swart.

(The Quantes XPS system. Photo:Supplied)

Explaining about the measurements, Prof Swart says: “This advanced X-ray photoelectron spectroscopy (XPS) instrument has the capability to analyse the very small area that the user is interested in and a large area of the uniform sample surface. The two different types of X-ray sources – the hard X-ray source and the more conventional soft X-ray source – can be switched automatically, allowing users to analyse the same area and/or points of a sample. The PHI Quantes XPS system ensures the availability of superior features such as automatic analysis, automatic sample transfer, turnkey charge neutralisation, and advanced data processing.”

“This XPS instrument is designed to pioneer new methods and applications transcending conventional ideas of what is possible.”

Optimising efficiency of materials

Prof Swart says the Department of Physics, especially the Research Chair in Advanced and Luminescent Materials, is developing new high-technology materials on a daily basis. “It is very important to know the chemical composition and defect distribution of the materials in order to add value to the fabrication of these materials,” he adds.

“The distribution of these defects is vital for the efficiency of the phosphor materials. If we know where these defects are located, we can determine the mechanisms of the light output coming from these phosphors,” describes Prof Swart.

Research conducted as part of the Research Chair in Solid State Luminescent and Advanced Materials will benefit significantly from this new system.

(Prof Koos Terblans, Head of the Department of Physics next to the Quantes XPS system. Photo:Supplied) 

“We are currently concentrating on phosphors as sensors (temperature), light-emitting diodes (LEDs), and solar cells, where we optimise the efficiency and durability of these materials. Any new knowledge, which I believe the PHI Quantes XPS system will provide us, will help us to reach our goal much quicker,” he says. 

Apart from the positive impact on research, the PHI Quantes XPS system will also be a benefit to society in the long term. Improved LEDs can be used to save electricity, and better solar cells can help to generate electricity, to mention but two examples. 

News Archive

Bloemfontein's quality of tap water compares very favourably with bottled water
2009-08-04

The quality of the drinking water of five suburbs in Bloemfontein is at least as good as or better than bottled water. This is the result of a standard and chemical bacterial analysis done by the University of the Free State’s (UFS) Centre for Environmental Management in collaboration with the Institute for Groundwater Studies (IGS).

Five samples were taken from tap water sources in the suburbs of Universitas, Brandwag, Bain’s Vlei, Langenhoven Park and Bayswater and 15 samples were taken of different brands of still and unflavoured bottled water. The samples were analysed at the laboratory of the IGS, while the interpretation of the analysis was done by the Centre for Environmental Management.

“We wanted to evaluate the difference in quality for human consumption between tap water and that of the different brands of bottled water,” said Prof. Maitland Seaman, Head of the Centre for Environmental Management.

“With the exception of two samples produced by multinational companies at their plants in South Africa, the different brands of bottled water used for the study were produced by South African companies, including a local small-scale Bloemfontein producer,” said Prof. Seaman.

According to the labels, the sources of the water vary from pure spring water, to partial reverse osmosis (as an aid to standardise salt, i.e. mineral, content), to only reverse osmosis (to remove salts). (Reverse osmosis is a process in which water is forced under pressure through a pipe with minute pores through which water passes but no – or very low concentrations of – salts pass.)

According to Prof. Seaman, the analysis revealed some interesting findings, such as:

• It is generally accepted that drinking water should have an acceptable level of salt content, as the body needs salts. Most mineral contents were relatively higher in the tap water samples than the bottled water samples and were very much within the acceptable range of drinkable water quality. One of the bottled samples, however, had a very low mineral content, as the water was produced by reverse osmosis, as stated on the bottle. While reverse osmosis is used by various producers, most producers use it as an aid, not as a single method to remove nearly all the salts. Drinking only such water over a prolonged period may probably have a negative effect on the human physiology.

• The pH values of the tap water samples (8,12–8,40) were found to be slightly higher (slightly alkaline), like in all south-eastern Free State rivers (from where the water is sourced) than the pH of most of the bottled water samples, most of which are sourced and/or treated in other areas. Two brands of bottled water were found to have relatively low pH levels (both 4,5, i.e. acidic) as indicated on their bottles and as confirmed by the IGS analysis. The health implication of this range of pH is not significant.

• The analysis showed differences in the mineral content given on the labels of most of the water bottles compared to that found by IGS analysis. The possibility of seasonal fluctuation in content, depending on various factors, is expected and most of the bottling companies also indicate this on their labels. What was a rather interesting finding was that two pairs of bottled water brands claimed exactly the same mineral content but appeared under different brand names and were also priced differently. In each case, one of the pair was a well-known house brand, and the other obviously the original producer. In one of these paired cases, the house brand stated that the water was spring water, while the other (identical) “original” brand stated that it was spring water treated by reverse osmosis and oxygen-enriched.

• Nitrate (NO3) levels were uniformly low except in one bottled sample, suggesting a low (non-threatening) level of organic pollution in the source water. Otherwise, none of the water showed any sign of pollution.

• The bacterial analysis confirmed the absence of any traces of coliforms or E.coli in any of the samples, as was also indicated by the bottling companies. This is very reassuring. What is not known is how all these waters were sterilised, which could be anything from irradiation to chlorine or ozone treatment.

• The price of the different brands of bottled water, each containing 500 ml of still water, ranged between R3,99 and R8,99, with R5,03 being the average price. A comparison between the least expensive and the most expensive bottles of water indicated no significant difference in quality. In fact, discrepancies were observed in the most expensive bottle in that the amount of Calcium (Ca) claimed to be present in it was found to be significantly different from what the analysis indicated (29,6 mg/l versus 0,92 mg/l). The alkalinity (CaCO3 mg/l) indicated on the bottle was also found to differ considerably (83 mg/l versus 9,4 mg/l). The concentration of Total Dissolved Salts (TDS) was not given on the product.

“The preference for bottled water as compared to Bloemfontein’s tap water from a qualitative perspective as well as the price discrepancy is unjustifiable. The environmental footprint of bottled water is also large. Sourcing, treating, bottling, packaging and transporting, to mention but a few of the steps involved in the processing of bottled water, entail a huge carbon footprint, as well as a large water footprint, because it also requires water for treating and rinsing to process bottled water,” said Prof. Seaman.

Media Release
Lacea Loader
Deputy Director: Media Liaison
Tel: 051 401 2584
Cell: 083 645 2454
E-mail: loaderl.stg@ufs.ac.za  
3 August 2009

 

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