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18 April 2022 | Story Leonie Bolleurs | Photo Stephen Collett
Prof Ted Kroon
Prof Ted Kroon from the Department of Physics recently delivered his inaugural lecture on the topic What’s the use of a rainbow on the UFS Bloemfontein Campus.

“A rainbow is a natural phenomenon, the result of the refraction and reflection of the sun’s rays in drops of rain. As far as mankind is concerned, it’s a perfectly useless object and won’t make anyone money. Yet the poet who said, My heart leaps up when I behold a rainbow in the sky, only put into word the feeling of wonder and excitement we all have when we see a rainbow.”

“Every day I see a rainbow in my work; I do not need to wait to see one in the sky,” says Prof Ted Kroon, Professor in the Department of Physics at the University of the Free State (UFS), who used this phenomenon to introduce the topic of his inaugural lecture: What’s the use of a rainbow. 

“Far from being only a colourful spectacle with no practical value, rainbows are useful – and lead to useful things,” he believes. 

According to Prof Kroon, one can find examples of real rainbows and rainbow analogies used not only in everyday life, but also in physics. “Besides it being familiar devices in literature, culture, and even marketing, studies of rainbows can yield practical engineering information and may even help us to find new habitable planets,” he says.

Inspired by the many uses of a rainbow

In his lecture, he discussed the basic features of natural rainbows and how they come about. He also explored how the rainbow gives meaning to colour, and how this relates to the temperature of objects. He looked at an array of instances where the rainbow is used; from depicting the life of a star to indicating that we are sick (a thermometer) or when we need to refill a gas cylinder.
Moreover, Prof Kroon pointed out that rainbows are used in computer chips, stress identification, and to transmit internet data through underwater cables of glass fibre. He also referred to how the rainbow was harnessed as an engineering tool to measure refractive index and characterise fine droplet sprays used in industry. 

He continues, “Remarkably, the science developed to understand the natural rainbow can be redirected and applied to the optical properties of metallic nanoparticles, allowing the development of nanotechnology. Knowing how the natural rainbow works and its limitations, better systems have been developed to produce rainbows. Such rainbows have been used to discover new elements and to determine the age of the universe.”

As a member of an international community of phosphor researchers who are privileged to work with rainbows every day, he has used them to study the light-emitting properties of materials doped with bismuth. With this project – an initiative with the African Laser Centre taking place between 2016 and 2021 – he collaborated with the University of Khartoum in Sudan and trained a number of its postgraduate students. “My role included the guidance of students and the measurement and interpretation of the light-emitting properties of the materials. Our research during this time, considering more than a dozen materials, was summarised in 34 scientific publications that contributed to a greater understanding of bismuth ions as light-emitting materials,” he explains. 

Developing new materials, efficient in emitting blue light

He has been developing luminescent materials since 2006, primarily for general lighting (fluorescent tubes and LEDs) and displays (television, computer, and cellphone screens), as well as niche applications in medical and forensic science. 

As part of his current research, he is examining the effect of plasmonic metal nanoparticles on phosphor light emission. He is also exploring materials that absorb infrared light but emit visible light. “For this, I would like to consider the long-term stability of such materials and develop new materials that are more efficient in emitting particularly blue light,” he says. 

Prof Kroon holds a C2 rating from the National Research Foundation and has published more than 150 articles and book chapters, obtaining a Scopus h-index of 26.

News Archive

New world-class Chemistry facilities at UFS
2011-11-22

 

A world-class research centre was introduced on Friday 18 November 2011 when the new Chemistry building on the Bloemfontein Campus of the University of the Free State (UFS) was officially opened.
The upgrading of the building, which has taken place over a period of five years, is the UFS’s largest single financial investment in a long time. The building itself has been renovated at a cost of R60 million and, together with the new equipment acquired, the total investment exceeds R110 million. The university has provided the major part of this, with valuable contributions from Sasol and the South African Research Foundation (NRF), which each contributed more than R20 million for different facets and projects.
The senior management of Sasol, NECSA (The South African Nuclear Energy Corporation), PETLabs Pharmaceuticals, and visitors from Sweden attended the opening.

Prof. Andreas Roodt, Head of the Department of Chemistry, states the department’s specialist research areas includes X-ray crystallography, electrochemistry, synthesis of new molecules, the development of new methods to determine rare elements, water purification, as well as the measurement of energy and temperatures responsible for phase changes in molecules, the development of agents to detect cancer and other defects in the body, and many more.

“We have top expertise in various fields, with some of the best equipment and currently competing with the best laboratories in the world. We have collaborative agreements with more than twenty national and international chemistry research groups of note.

“Currently we are providing inputs about technical aspects of the acid mine water in Johannesburg and vicinity, as well as the fracking in the Karoo in order to release shale gas.”

New equipment installed during the upgrading action comprises:

  • X-ray diffractometers (R5 million) for crystal research. Crystals with unknown compounds are researched on an X-ray diffractometer, which determines the distances in angstroms (1 angstrom is a ten-billionth of a metre) and corners between atoms, as well as the arrangement of the atoms in the crystal, and the precise composition of the molecules in the crystal.
  • Differential scanning calorimeter (DSC) for thermographic analyses (R4 million). Heat transfer and the accompanying changes, as in volcanoes, and catalytic reactions for new motor petrol are researched. Temperature changes, coupled with the phase switchover of fluid crystals (liquid crystals -watches, TV screens) of solid matter to fluids, are measured.
  • Nuclear-magnetic resonance (NMR: Bruker 600 MHz; R12 million, one of the most advanced systems in Africa). A NMR apparatus is closely linked with the apparatus for magnetic resonance imaging, which is commonly used in hospitals. NMR is also used to determine the structure of unknown compounds, as well as the purity of the sample. Important structural characteristics of molecules can also be identified, which is extremely important if this molecule is to be used as medication, as well as to predict any possible side effects of it.
  • High-performance Computing Centre (HPC, R5 million). The UFS’ HPC consists of approximately 900 computer cores (equal to 900 ordinary personal computers) encapsulated in one compact system handling calculations at a billion-datapoint level It is used to calculate the geometry and spatial arrangements, energy and characteristics of molecules. The bigger the molecule that is worked with, the more powerful the computers must be doing the calculations. Computing chemistry is particularly useful to calculate molecular characteristics in the absence of X-ray crystallographic or other structural information. Some reactions are so quick that the intermediary products cannot be characterised and computing chemistry is of invaluable value in that case.
  • Catalytic and high-pressure equipment (R6 million; some of the most advanced equipment in the world). The pressures reached (in comparison with those in car tyres) are in gases (100 times bigger) and in fluids (1 500 times) in order to study very special reactions. The research is undertaken, some of which are in collaboration with Sasol, to develop new petrol and petrol additives and add value to local chemicals.
  • Reaction speed equipment (Kinetics: R5 million; some of the most advanced equipment in the world). The tempo and reactions can be studied in the ultraviolet, visible and infrared area at millisecond level; if combined with the NMR, up to a microsecond level (one millionth of a second.

Typical reactions are, for example, the human respiratory system, the absorption of agents in the brain, decomposition of nanomaterials and protein, acid and basis polymerisation reactions (shaping of water-bottle plastic) and many more.

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