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23 June 2021 | Story Leonie Bolleurs | Photo Supplied
The Department of Engineering Sciences (EnSci) – under the leadership of Dr Abdolhossein Naghizadeh – is heading a collaboration of scientists to create a green concrete that will reduce the impact of cement on the environment.

Conventional cement production is responsible for more than 6% of the overall carbon emissions in the world, which ultimately affects global warming.

The Department of Engineering Sciences (EnSci) at the University of the Free State (UFS) – under the leadership of Dr Abdolhossein Naghizadeh – is heading a collaboration of scientists from universities in South Africa and abroad to create a green concrete that will reduce the impact of cement on the environment.

This product has the potential to be used as an alternative to conventional concrete in large-scale constructions such as residential buildings and infrastructure, as well as small-scale constructions such a pavements and brickworks. 

Dr Nagizadeh, whose passion is cement and green concrete, says the idea of eco-friendly concrete was considered by European researchers a few years ago; however, this technology is still in its initial stages and has not been researched and employed at industrial scale yet. He believes that it is due to the complexity of the preparation process, and the relatively aggressive chemicals used in green concrete mixtures.

Expertise and equipment 

With his knowledge and experience of the product, Dr Naghizadeh – who joined EnSci in 2020 – has been appointed project leader of a collaborative group of scientists from the Universities of Johannesburg, KwaZulu-Natal, Yaoundé in Cameroon, and the Erzurum Technical University in Turkey.  

“Since there are only a limited number of researchers in this field, EnSci is benefiting from the expertise of this international collaboration. The proficiency of this group of scientists are keeping the project current, based on the latest findings in the research area,” says Louis Lagrange, Head of the Department of Engineering Sciences. 

Based on this new capacity, the department decided to establish and equip a new laboratory facility dedicated to cement and concrete research, with a specific current focus on green concrete. 

In this laboratory, they want to create formulations of green concrete, based on user-friendly materials. Furthermore, they aim to simplify the preparation and mixing process. “This can introduce a more eco-friendly, desirable product that can easily be employed extensively in the construction industry,” says Lagrange.

Benefits and other advantages

Besides its ability to reduce the impact on the environment through reduced carbon emissions, the product is also described to perform at equal or even superior strength and durability compared to conventional concrete, with potentially substantial environmental and economic benefits. 

This product is also primarily made from waste materials or industrial by-products. Dr Naghizadeh explains it as follows: “Normal concrete consists of conventional (Portland) cement, sand, stone and water, while in green concrete the conventional cement part of the concrete mix is replaced by industrial wastes or by-products and alkali solutions. These alternative materials are mostly aluminosilicate materials such as fly ash (residue from coal burning process in power plants) and slag (waste material from iron extraction processes).”

“Using these waste substances as binding material in green concrete can, apart from the environmental benefits, also reduce waste and contribute to the circular economy. Annually, more than 36 million tons of fly ash are produced in South Africa alone, of which more than 90% is deposited at landfill sites. Reuse of these waste materials will moderate the related waste deposition issues, such as air and groundwater pollution.”

Production of green concrete

Currently, green concrete is mostly produced in two parts: a solid raw material and an alkali activation solution. With their project, the research group wants to develop green concrete in a powdered form, to be mixed with water, instead of a chemical. Dr Nagizadeh estimates that the construction industry will be able to benefit from their work in about two years’ time when they will have a user-friendly green concrete product ready. 

Apart from putting an eco-friendlier concrete on the market, this project is also establishing a brand-new research niche in the UFS Department of Engineering Sciences. According to Lagrange, this research has the ability to attract postgraduate students and other researchers. He is also looking forward to the international academic recognition that EnSci will receive through published articles in leading international journals, and the participation of researchers in accredited conferences arising from this project. 

Lagrange is pleased that the project is establishing EnSci as a research player of note in the engineering field, specifically in the green engineering field. 

News Archive

New world-class Chemistry facilities at UFS
2011-11-22

 

A world-class research centre was introduced on Friday 18 November 2011 when the new Chemistry building on the Bloemfontein Campus of the University of the Free State (UFS) was officially opened.
The upgrading of the building, which has taken place over a period of five years, is the UFS’s largest single financial investment in a long time. The building itself has been renovated at a cost of R60 million and, together with the new equipment acquired, the total investment exceeds R110 million. The university has provided the major part of this, with valuable contributions from Sasol and the South African Research Foundation (NRF), which each contributed more than R20 million for different facets and projects.
The senior management of Sasol, NECSA (The South African Nuclear Energy Corporation), PETLabs Pharmaceuticals, and visitors from Sweden attended the opening.

Prof. Andreas Roodt, Head of the Department of Chemistry, states the department’s specialist research areas includes X-ray crystallography, electrochemistry, synthesis of new molecules, the development of new methods to determine rare elements, water purification, as well as the measurement of energy and temperatures responsible for phase changes in molecules, the development of agents to detect cancer and other defects in the body, and many more.

“We have top expertise in various fields, with some of the best equipment and currently competing with the best laboratories in the world. We have collaborative agreements with more than twenty national and international chemistry research groups of note.

“Currently we are providing inputs about technical aspects of the acid mine water in Johannesburg and vicinity, as well as the fracking in the Karoo in order to release shale gas.”

New equipment installed during the upgrading action comprises:

  • X-ray diffractometers (R5 million) for crystal research. Crystals with unknown compounds are researched on an X-ray diffractometer, which determines the distances in angstroms (1 angstrom is a ten-billionth of a metre) and corners between atoms, as well as the arrangement of the atoms in the crystal, and the precise composition of the molecules in the crystal.
  • Differential scanning calorimeter (DSC) for thermographic analyses (R4 million). Heat transfer and the accompanying changes, as in volcanoes, and catalytic reactions for new motor petrol are researched. Temperature changes, coupled with the phase switchover of fluid crystals (liquid crystals -watches, TV screens) of solid matter to fluids, are measured.
  • Nuclear-magnetic resonance (NMR: Bruker 600 MHz; R12 million, one of the most advanced systems in Africa). A NMR apparatus is closely linked with the apparatus for magnetic resonance imaging, which is commonly used in hospitals. NMR is also used to determine the structure of unknown compounds, as well as the purity of the sample. Important structural characteristics of molecules can also be identified, which is extremely important if this molecule is to be used as medication, as well as to predict any possible side effects of it.
  • High-performance Computing Centre (HPC, R5 million). The UFS’ HPC consists of approximately 900 computer cores (equal to 900 ordinary personal computers) encapsulated in one compact system handling calculations at a billion-datapoint level It is used to calculate the geometry and spatial arrangements, energy and characteristics of molecules. The bigger the molecule that is worked with, the more powerful the computers must be doing the calculations. Computing chemistry is particularly useful to calculate molecular characteristics in the absence of X-ray crystallographic or other structural information. Some reactions are so quick that the intermediary products cannot be characterised and computing chemistry is of invaluable value in that case.
  • Catalytic and high-pressure equipment (R6 million; some of the most advanced equipment in the world). The pressures reached (in comparison with those in car tyres) are in gases (100 times bigger) and in fluids (1 500 times) in order to study very special reactions. The research is undertaken, some of which are in collaboration with Sasol, to develop new petrol and petrol additives and add value to local chemicals.
  • Reaction speed equipment (Kinetics: R5 million; some of the most advanced equipment in the world). The tempo and reactions can be studied in the ultraviolet, visible and infrared area at millisecond level; if combined with the NMR, up to a microsecond level (one millionth of a second.

Typical reactions are, for example, the human respiratory system, the absorption of agents in the brain, decomposition of nanomaterials and protein, acid and basis polymerisation reactions (shaping of water-bottle plastic) and many more.

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