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29 November 2022 | Story Leonie Bolleurs | Photo Leonie Bolleurs
UFS green concrete
The Department of Engineering Sciences (EnSci) welcomes collaborations with other departments at the UFS. Pictured here are, from the left: Louis Lagrange, Head of EnSci, Prof Kahilu Kajimo-Shakantu, Head of the Department of Quantity Surveying and Construction Management, Dr Abdolhossein Naghizadeh, and Megan Welman-Purchase, analytical scientist in the Department of Geology.

More than 30 million tonnes of fly ash (residue from coal combustion in power plants) are generated in South Africa annually, with 96% of that being disposed of in landfills. There is thus more than enough of this key ingredient to produce green concrete. 

Green concrete, so called due to its environmentally friendly benefits, is an eco-friendly alternative to conventional concrete based on the Portland cement binder. During the production of green concrete, less carbon dioxide is released into the atmosphere than with the production of ordinary Portland cement (OPC). The latter accounts for up to 8% of all global carbon emissions.

Successful tests

In the Green Concrete Lab, established in 2021 within the Department of Engineering Sciences (EnSci) on the Bloemfontein Campus of the University of the Free State (UFS), Dr Abdolhossein Naghizadeh, Senior Lecturer, researcher, and engineer, is working on green cement and concrete projects.

He uses ‘geopolymer’ technology and a mix of waste materials, alkaline solutions, and recycled aggregates to form concrete mixtures that can provide properties similar to conventional concrete.

Besides being a synthesised inorganic material (not a petrochemical product), the geopolymer cement he introduced has the following properties: it is made from a reaction between aluminosilicate materials and strong alkalis (5-7% of the concrete mixture), it uses water and by-products as raw materials, it does not calcinate lime, thus giving it a low carbon emission, and it is also beneficial from a waste management point of view. 

The waste materials used can include waste from industrial and agricultural sources, such as fly ash, rice husk ash, sugar-cane bagasse, or corncob ash, as well as natural materials such as volcanic ash. In South Africa, sufficient amounts of industrial and agricultural waste are available. 

“So far, we have successfully tested various types of green concrete based on different waste materials,” says Dr Naghizadeh. 

Besides researching the green mixture proportions in the lab, Dr Naghizadeh and his students focused their attention on establishing the strength, durability, workability, and production cost of the product. 

They compared green concrete with conventional concrete. Green concrete’s workability is slightly lower (but he believes that with appropriate mix design it can be corrected), and it has a much higher compressive strength (50-90 MPa), a smaller carbon footprint, and comparable production costs to conventional concrete (depending on the mix design). A very high level of resistance against alkali-silica reaction (concrete cancer) is also present, as well as resistance to carbonation, sulphate attack, and acid attack.
So far, we have successfully tested various types of green concrete based on different waste materials.– Dr Naghizadeh. 

He explains, “The superior durability performance of green concrete is related to its chemical compositions and microstructure. For example, the lack of calcium content in the composition provides better resistance to alkali-silica reaction. At the same time, stronger bonds between elements and polymeric microstructure provide better resistance against acids and fire.”

With all the work and research of the past year and a half, Dr Naghizadeh says they are at the stage where they can prescribe green concrete production recipes for the industry parties based on the specified application and the materials they have.

Biggest accomplishments

“We transferred most of the experimental works to the Green Concrete Lab at the beginning of 2022, which improved our productivity tremendously. Since then, nine journal papers and three peer-reviewed conference papers have been published as outputs of the research projects. Currently, there are also multiple publications under review or in the development stages,” says Dr Naghizadeh.

In addition to him, there are three master's students and one research associate working on their own individual projects.

The department is very proud of its research outputs. Dr Naghizadeh was either author or co-author of all 12 research papers. The focus of these papers was mostly on the formulation of green concrete, based on locally available agricultural waste materials, the formulation of one-part geopolymer cement (when aluminosilicate raw material is replaced with pre-activated aluminosilicate material, water can be used instead of alkali solution), and the development of ambient-cured green concrete (replacing the aluminosilicate raw material with a blend of materials).

Dr Naghizadeh is also the project leader of a group of scientists from local and international universities who are researching sustainable construction materials. These institutions include the Universities of Johannesburg, KwaZulu-Natal, Yaoundé in Cameroon, Erzurum Technical University in Turkey, as well as Nelson Mandela University and the Central University of Technology, which recently came on board. 

 


 


News Archive

UFS involved in project to light up the townships
2006-06-06

The parties involved with the project are from the left: Prof Hendrik Swart (Departmental Chairperson of the UFS Department of Physics), Dr Thembela Hillie (CSIR), Prof Neerich Revaprasadu (Department of Chemistry at the University of Zululand) and Dr Wynand Steyn (CSIR).

UFS involved in project that could light up the townships   

The University of the Free State’s (UFS) Department of Physics is involved with a project that could make life easier in the townships through the use of artificial light.

“The project is based on the use of sunlight to activate nano material in for example cement and paint during the day. At night the cement or paint can then radiate light,” said Prof Hendrik Swart, Departmental Chairperson of the UFS Department of Physics.

According to Prof Swart an amount of R3,9 million has been made available by the Council for Scientific and Industrial Research (CSIR) for the further development of the project.   

Prof Swart visited the University of Florida in America in 1995 for a year where he researched luminescent phosphor material that is suitable for flat panel television screens.  The red, green and blue spots on the television screens originate from these kinds of phosphor materials.  “At that stage plasma television screens were only a dream.  Today it is sold everywhere,” said Prof Swart. 

“Upon my return I started a research group at the UFS which investigated the degrading of phosphor material.  We also started to concentrate on the effectiveness of nano phosphors.  In the mean time our cooperation with the Americans was strengthened with follow-up visits to America of my colleagues, Prof Koos Terblans and Mr Martin Ntwaeaborwa,” said Prof Swart.

“Nano phosphors are basically luminescent powders that consist of particles that are 1 millionth of a millimetre.  These particles can provide light as soon as they are illuminated with, for instance, sunlight.  The amount of time these particles can provide light, is determined by the impurities in the material,” said Prof Swart.

According to Prof Swart nano particles are developed and linked to infrastructure materials in order for these materials to be excited during the day by sunlight and then it emits light during night time.

“The nano material is of such a nature that it can be mixed with materials, such as paint or cement. The yellow lines of roads can for example emit light in a natural way during night time,” said Prof Swart.

About a year ago Prof Swart and Dr Thembela Hillie, a former Ph D-student of the UFS Department of Physics, had discussions with Prof Neerich Revaprasadu from the University of Zululand and the CSIR about the possibility of mixing these nano phosphor particles with other materials that can be used as light sources in the building of roads and houses.

“Prof Revaprasadu is also actively involved in the research of nano materials.  Our efforts resulted in the CSIR approving the further extension of the project,” said Prof Swart.   

“The UFS and the University of Zululand are currently busy investigating ways to extend the light emitting time,” said Prof Swart.  

“There are eight M Sc and Ph D-students from the UFS and about five students from the University of Zululand working on this research project.  The Department of Physics at the Qwaqwa Campus of the UFS, with Francis Dejene as subject head, is also involved with the project,” said Prof Swart.

According to Prof Swart the further applications of nano materials are unlimited.  “Children whose parents cannot afford electricity can for instance leave any object such as a lamp, that is covered with these phosphor particles, in the sun during the day and use it at night as a light for study purposes,” said Prof Swart.

According to Prof Swart the further extension of the project will take about two years.  “During this time we want to determine how the effectiveness of the phosphors can be increased.  Discussions with the government and other role players for the possible implementation of the project are also part of our planning,” said Prof Swart.


Media release
Issued by: Lacea Loader
Media Representative
Tel:   (051) 401-2584
Cell:  083 645 2454
E-mail:  loaderl.stg@mail.uovs.ac.za
6 June 2006

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