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29 November 2022 | Story Leonie Bolleurs | Photo Leonie Bolleurs
UFS green concrete
The Department of Engineering Sciences (EnSci) welcomes collaborations with other departments at the UFS. Pictured here are, from the left: Louis Lagrange, Head of EnSci, Prof Kahilu Kajimo-Shakantu, Head of the Department of Quantity Surveying and Construction Management, Dr Abdolhossein Naghizadeh, and Megan Welman-Purchase, analytical scientist in the Department of Geology.

More than 30 million tonnes of fly ash (residue from coal combustion in power plants) are generated in South Africa annually, with 96% of that being disposed of in landfills. There is thus more than enough of this key ingredient to produce green concrete. 

Green concrete, so called due to its environmentally friendly benefits, is an eco-friendly alternative to conventional concrete based on the Portland cement binder. During the production of green concrete, less carbon dioxide is released into the atmosphere than with the production of ordinary Portland cement (OPC). The latter accounts for up to 8% of all global carbon emissions.

Successful tests

In the Green Concrete Lab, established in 2021 within the Department of Engineering Sciences (EnSci) on the Bloemfontein Campus of the University of the Free State (UFS), Dr Abdolhossein Naghizadeh, Senior Lecturer, researcher, and engineer, is working on green cement and concrete projects.

He uses ‘geopolymer’ technology and a mix of waste materials, alkaline solutions, and recycled aggregates to form concrete mixtures that can provide properties similar to conventional concrete.

Besides being a synthesised inorganic material (not a petrochemical product), the geopolymer cement he introduced has the following properties: it is made from a reaction between aluminosilicate materials and strong alkalis (5-7% of the concrete mixture), it uses water and by-products as raw materials, it does not calcinate lime, thus giving it a low carbon emission, and it is also beneficial from a waste management point of view. 

The waste materials used can include waste from industrial and agricultural sources, such as fly ash, rice husk ash, sugar-cane bagasse, or corncob ash, as well as natural materials such as volcanic ash. In South Africa, sufficient amounts of industrial and agricultural waste are available. 

“So far, we have successfully tested various types of green concrete based on different waste materials,” says Dr Naghizadeh. 

Besides researching the green mixture proportions in the lab, Dr Naghizadeh and his students focused their attention on establishing the strength, durability, workability, and production cost of the product. 

They compared green concrete with conventional concrete. Green concrete’s workability is slightly lower (but he believes that with appropriate mix design it can be corrected), and it has a much higher compressive strength (50-90 MPa), a smaller carbon footprint, and comparable production costs to conventional concrete (depending on the mix design). A very high level of resistance against alkali-silica reaction (concrete cancer) is also present, as well as resistance to carbonation, sulphate attack, and acid attack.
So far, we have successfully tested various types of green concrete based on different waste materials.– Dr Naghizadeh. 

He explains, “The superior durability performance of green concrete is related to its chemical compositions and microstructure. For example, the lack of calcium content in the composition provides better resistance to alkali-silica reaction. At the same time, stronger bonds between elements and polymeric microstructure provide better resistance against acids and fire.”

With all the work and research of the past year and a half, Dr Naghizadeh says they are at the stage where they can prescribe green concrete production recipes for the industry parties based on the specified application and the materials they have.

Biggest accomplishments

“We transferred most of the experimental works to the Green Concrete Lab at the beginning of 2022, which improved our productivity tremendously. Since then, nine journal papers and three peer-reviewed conference papers have been published as outputs of the research projects. Currently, there are also multiple publications under review or in the development stages,” says Dr Naghizadeh.

In addition to him, there are three master's students and one research associate working on their own individual projects.

The department is very proud of its research outputs. Dr Naghizadeh was either author or co-author of all 12 research papers. The focus of these papers was mostly on the formulation of green concrete, based on locally available agricultural waste materials, the formulation of one-part geopolymer cement (when aluminosilicate raw material is replaced with pre-activated aluminosilicate material, water can be used instead of alkali solution), and the development of ambient-cured green concrete (replacing the aluminosilicate raw material with a blend of materials).

Dr Naghizadeh is also the project leader of a group of scientists from local and international universities who are researching sustainable construction materials. These institutions include the Universities of Johannesburg, KwaZulu-Natal, Yaoundé in Cameroon, Erzurum Technical University in Turkey, as well as Nelson Mandela University and the Central University of Technology, which recently came on board. 

 


 


News Archive

Linguistic resourcefulness impresses at 15th Student Symposium on the Natural Sciences
2015-11-26


UFS students walk away with more than half the prizes at this year’s Student Symposium on the Natural Sciences.

This year, the fifteenth annual Student Symposium on the Natural Sciences was hosted on the Bloemfontein Campus by the UFS Departments of Chemistry and Physics, together with the South African Academy for Science and Arts (SAAWK).

According to Dr Ernie Langner, Senior Lecturer in the Department of Chemistry, this symposium provides postgraduate students from all over South Africa the opportunity to present their research in Afrikaans, to learn from each other, receive feedback on their work through the review process, and to build networks. If their abstracts are selected for publication in the Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie, it also provides them with further exposure in the broader academic context.

Besides research of the highest quality, this year's symposium had no shortage of linguistic resourcefulness. “Students, accustomed to writing and expressing their research in English, astonished everybody with their beautiful Afrikaans. Outstanding research from honours, master's, and doctoral students was expressed in scientific terminology of the highest standard,” Dr Langner said.

The Student Symposium is the only event (worldwide) where the development of 'elektrostatiese potensiaalkaarte', 'femtosekonde pomp-proef spektroskopie', or 'endokrien-ontwrigtende chemikalieë' is explained step by step. This is where one hears enthusiastic students talking about how hard they are working on 'geïntegreerde drywende sonkragstelsels', or 'geneste virtuele rekenaars binne die wolkstelsel'. The results of hours of hard work in the lab, cold nights behind a telescope, or long midnight sessions in front of the computer, had to be condensed into 15-minute presentations on the synthesis of metal-organic networks, or metal-carbene complexes, the identification of pulsar rhythms, or the refining of rapid-eye technology.

Of approximately forty participants from five universities, eighteen were awarded prizes for their papers and posters. Students from the UFS walked away with more than half of the awards. Jacques Maritz (Physics) and his wife, Elizabeth, (Mathematics and Applied Mathematics) from the UFS were both awarded first place in their respective sessions.

 

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