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Research into biodegradable polymers helps fight plastic pollution

02 September 2024 | Story André Damons | Photo Supplied

Dr Puseletso Mofokeng — Dr Julia Puseletso Mofokeng, from the UFS’s Department of Chemistry, is doing research into biodegradable polymers for application in disposable product packaging.

A researcher from the University of the Free State (UFS) is contributing to the fight against plastic pollution through her research into biodegradable polymers – large, chain-like molecules – as a more environmentally friendly alternative to petroleum-based plastics.

Plastic pollution is a global environmental problem, with 19 to 23 million tonnes of plastic waste leaked into aquatic ecosystems every year.

Dr Julia Puseletso Mofokeng, Senior Lecturer and Researcher in the UFS Department of Chemistry, hopes her research into how biodegradable polymers can be used in disposable product packaging can influence the industry and policymakers to enforce the use of biopolymers or biodegradable polymers in disposable products. This would help reduce plastic waste and boost environment-conservation efforts.

The United Nations Environment Programme (UNEP) describes plastic waste as a serious environmental problem – humans produce about 400 million tonnes of plastic waste every year. Approximately 36% of all plastics produced are used in packaging, including single-use plastic products for food and beverage containers, approximately 85% of which ends up in landfills or as unregulated waste.

Researching biodegradable polymers

Dr Mofokeng’s desire to solve the waste problem in her community of Bophelong village in Qwaqwa, Free State – where community members dumped and burned all sorts of waste, including plastics – inspired her towards her field of research.

Today, her research is aimed at managing plastic waste to combat environmental and atmospheric pollution (from incineration), conserve energy, and improve water quality, including ensuring safe drinking water.

High levels of plastic waste have led to increased research into and development of biodegradable polymers as an alternative to non-biodegradable materials for short-shelf-life goods (such as packaging for fresh fruit and vegetables).

Biopolymers or biodegradable polymers, explains Dr Mofokeng, are derived from renewable resources including, but not limited to, vegetable oils, starches and animal fats. They can therefore be easily disposed of after use without harming the environment.

“My research is based on the preparation and characterisation of completely biodegradable polymers, their blends, and composites or nanocomposites filled with unmodified or modified inorganic fillers, natural fibres, as well as synthesised carbonaceous materials,” she says.

Such materials are developed for various applications, including packaging, electromagnetic interference shielding (blocking unwanted signals), and the removal of heavy metals and other contaminants from water bodies.

“To achieve these aims, I and my small research group are preparing completely biodegradable polymer blends.”

This involves adjusting their morphology (structure) and some of their properties (thermal, thermomechanical, mechanical, and flame retardancy) to match those of petroleum-based polymers in their replacement for disposable products; by reinforcing with natural fibres, and minerals.

Biodegradable polymers can degrade within a few days to a few years depending on their source, type, and biodegradation method used, while petroleum-based polymers can exist for hundreds to thousands of years without degrading. Moreover, because biodegradable polymers are produced from natural resources, their biodegradation mainly produces carbon dioxide, water, and other non-toxic byproducts, Dr Mofokeng adds.

“Biodegradable polymers can degrade by themselves under natural environmental conditions – in one to three years – or may require human intervention to degrade where composts are prepared or conditions are controlled in order to degrade the polymers. The latter two being the fastest, where it could take days to months. In my previous research project [we] kept polylactic acid filled with short sisal fibre in plain water at 80℃, and all the tested samples degraded within 10 days.”

She and a PhD student are conducting an ongoing experiment involving three different biodegradable polymer systems exposed to different conditions outside and under soil, measuring the rate of biodegradation by mimicking the environmental conditions found in dumping sites and landfills.

Signs of biodegradation on the samples showed clearly after 14 months, with cracks, surface erosion, and a decrease in the initial weighed mass, suggesting that the polymers could be completely degraded within two to three years.

Closer to goal

Dr Mofokeng, who has been a National Research Foundation (NRF) Y2-rated researcher since 2021, says since most food outlets and restaurants in South Africa have already started using paper- and bio-based polymer materials in cutlery, straws, and takeaway packaging, the country seems to be closer to its goal of using biodegradable polymers for disposable packaging.

The UFS, too, is aiming to phase out the use of plastic bottles in the next three to five years. This will be done by installing filtered water machines in all its buildings.

“We are now left with policymakers to enforce strict laws governing production; and retail industries to use biopolymers or biodegradable polymers in disposable packaging materials,” she says.

New research

Dr Mofokeng and her group’s research is in line with the United Nations’ Sustainable Development Goals (SDGs), including ensuring good health and wellbeing (SDG3), providing clean water and sanitation (SDG6), forging sustainable cities and communities (SDG11), establishing sustainable consumption and production patterns (SDG12), and protecting life below water (SDG14).

She has been researching polymers for almost two decades, and remains passionate about her research field and educating communities. Her new research project, in collaboration with colleagues from her department, targets the removal of heavy metals and other contaminants from groundwater. Testing and water treatment is set to take place in different regions in Qwaqwa, specifically among households that collect drinking and cooking water from boreholes.

Dr Mofokeng’s research group was established in 2016 with one honours and two master’s students. She has since supervised nine honours, seven master’s and one PhD student.

She also recently established international research collaborations with the Libyan Advanced Center for Chemical Analysis and the Faculty of Technology at the University of Banja Luka in Serbia.

News Archive

UFS awards degrees at autumn graduation ceremony

2009-04-28

The University of the Free State’s (UFS) autumn diploma and graduation ceremony took place this week in the Arena on the South Campus in Bloemfontein (formerly known as the Vista Campus). This arrangement has been made because of the large-scale renovations to the Callie Human Centre on the Main Campus.

Friday, 24 April 2009
Faculties of Health Sciences, Law and Theology Diploma ceremony

Law student’s achievement excels 80%
Four Law students obtained the LLB degree at this year’s autumn graduation ceremony of the University of the Free State (UFS) summa cum laude and were awarded the Moritz Bobbert Medal. They are from the left: Lezelle Olivier (80%), Albert Nell (91%) and Amanda du Toit (83%). LiFeng Chien were absent during the photo.

UFS awards degrees at autumn graduation ceremony
Today 331 students and five doctorates in the Faculties of Health Sciences, Law and Theology received their qualifications at this year’s autumn graduation ceremony of the University of the Free State (UFS). Michael Molahloe (left) and Mamokete Ntholeng both received their LL.B. degrees in the Faculty of Law.
Photo: Leonie Bolleurs

This year’s autumn graduation ceremony of the University of the Free State (UFS) was held on the South Campus. From the group of students that received their qualification from the Faculty of Law, is from the left: Janine Jonson, Anneska van der Spoel, Andrea Coetzer, and Jo-Mari Visser.
Photo: Leonie Bolleurs

Students in Nursing receive their degree
A group of students from the Faculty of Health Sciences received their B.Soc.Sc. degree at this year’s autumn graduation ceremony of the University of the Free State (UFS). At the occasion were, from the left: Ruth Beukes, Basetsana Panana, and Dipontsheng Tsolo.
Photo: Leonie Bolleurs

UFS Faculty of Health Sciences awards degrees
Liezl Swanepoel (left) and Heide van der Merwe received their BSocSC degrees at the University of the Free State’s (UFS) autumn graduation ceremony.
Photo: Leonie Bolleurs

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Thursday, 23 April 2009
Faculty of Natural and Agricultural Sciences & Chancellor’s Dinner

UFS awards unique doctorate
Dr Rodney Douglas, who had never obtained any formal undergraduate qualification, this week received a Ph.D. in Geography and Geology during the autumn graduation ceremony of the University of the Free State (UFS). The name of his thesis is “A new perspective on the geohydrological and surface processes controlling the depositional environment at the Florisbad archaeozoological site”. He had four papers published in journals that were related to his thesis. He obtained his South African Museums Association Diploma in Biology in 1988 and his M.Sc. in Environmental Biology at the University of Natal, Durban in 1992. He was accepted as a Master's degree student at that university based on research that he had conducted on, amongst others, the diets of reptiles. He has been working at the Department of Herpetology at the National Museum, Bloemfontein since 1984, where he holds the post of Principal Museum Scientist and Head of Department.
Photo: Leonie Bolleurs

Chancellor’s Dinner: UFS honours doctoral students
Last night, the University of the Free State (UFS) honoured students who had received their Ph.D. degrees at the autumn graduation ceremony this past week, at the Chancellor’s Dinner. A total of 25 doctorates were awarded during the respective ceremonies. Attending the occasion were, from the left: Dr Annemarie Kühn, Ph.D. in Chemistry, Prof. Jeanet Conradie, Department of Chemistry at the UFS and Dr Kühn’s promoter, Prof. Teuns Verschoor, Acting Rector of the UFS, Prof. Corene de Wet, Department of Comparative Education and Education Management at the UFS, and Dr Mafu Rakometsi, Chief Executive Officer of Umalusi and former head of the Free State Department of Education who received a Ph.D. in History. Prof. De Wet is Dr Rakometsi's co-promoter and the late Prof. Leo Barnard, former Head of the Department of History at the UFS, who passed away at the beginning of April 2009, was his promoter.
Photo: Leonie Bolleurs

Mrs Annemarie Kilian, Mr Willem Kilian (BSc. Hons) and Prof Stephanus Kilian
Photo: Mangaliso Radebe

Mr Jaco van der Merwe, Mr Renico Pretorius and Mr Rion Terblanche (all BSc. Quantity Survying)
Photo: Mangaliso Radebe

Ms Mamakoanyane Amelia Shata (BSc. Genetics and BSc. Hons. Plant Molecular Biology) and Mrs Maente Adelinah Shata.
Photo: Mangaliso Radebe

Mr Maurice Ambrose and Mr Owen Monk (both BSc. Quantity Survying).
Photo: Mangaliso Radebe

Ms Tobeka Mehlomekhulu (Lecturer: Department of Geography), Mr Neo Mokgosi (BSc. Hons. Genetics) and Ms Nwabisa Mehlomekhulu (BSc. Hons. Food Science).
Photo: Mangaliso Radebe

Mr John Mdane, Mr Fana Mdane (BSc. Information Technology) and Mrs Agnes Mdane
Photo: Mangaliso Radebe

Mr Kevin Vermaak (BSc. Hons. Geohydrology) and Ms Michelle Steenkamp (BSc. Hons. Geology).
Photo: Mangaliso Radebe

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21 April 2009
Faculty of Economic and Management Sciences

Prof. Magda Fourie's daughter graduates
Nadia Fourie, daughter of Prof. Magda Fourie, former Vice-Rector: Academic Planning at the UFS and now Vice-Rector: Teaching at Stellenbosch University, received the B.Com. Law degree.
Photo: Lacea Loader

724 degrees were awarded during the ceremony of the Faculty of Economic and Management Sciences. Here are, from the left: Simon Serutla, B.Com. Accounting, Lourencia Hamuaka, B.Com. Honours in Financial Economics and Investment Management, Sunet Opperman, B. Accounting, and Yolandi Greyling, B. Accounting.
Photo: Lacea Loader

Students in the Faculty of Economic and Management Sciences graduated this week during the University of the Free State's (UFS) autumn graduation ceremony. Altogether 724 degrees were conferred. Here are, from the left: Marie-Louise Lombard, B.Com. Law, Adriaan van der Merwe, B.Com. Law and member of the Student Representative Council (Legal and Constitutional Affairs), Basanio Ncike, B.Com. Economics, and Richard Schooling, B.Com. Banking.
Photo: Lacea Loader

Center for Accounting honours top achievers
The Centre for Accounting at the University of the Free State (UFS) honoured the top ten students in the third-year B.Com. and B.Com. Hons. programmes respectively during this week's autumn graduation ceremony. Here are, from the left: Prof. Ronell Britz, Chairperson of the centre, Nils Kotze, first place in the B.Com. third-year group, and Madri Victor, first place in the B.Com. Hons. group; back: Prof. Hentie van Wyk, Programme Director: Accountant Training.
Photo: Stephen Collett

Accounting firms in Free State help with recognition of top achievers
Accounting firms in the Free State have contributed to a fund at the University of the Free State’s (UFS) Centre for Accounting to give recognition to top achievers in the third-year programme for the B.Com. and B.Com Hons. degrees respectively this week. It is evidence of the good relationship that exists between the Centre and the South African Institute for Chartered Accountants (SAICA), Free State. Here, from the left, are: Mr Pieter Clase, CoetzeeSmit Chartered Accountants, Mr Oswald Wentworth, KPMG, Mr Ettienne van Niekerk, PricewaterhouseCoopers, Herman Leach, Gobodo Inc. Chartered Accountants, and Mr Stefan Strydom, Havenga, Rossouw & Viljoen; front: Mr Ian Smit, Enslins Bloemfontein, Ms Thelma Crossman, Mazars, and Ms Daphline O'Brien, Ernst & Young.
Photo: Stephen Collett

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20 April 2009
Faculty of Education, Faculty of the Humanities.

CHESD awards 15 masters degrees
A group of 15 students received the Structured M.A. (Higher Education Studies) of the Centre for Higher Education Studies and Development (CHESD) at this year’s autumn graduation ceremony of the University of the Free State (UFS). This is the biggest group in the centre's history to be awarded master’s degrees, while four of the students received distinctions. Also of interest is that six of the 15 students already have doctoral degrees. At the occasion were, from the left: Dr Dipane Hlalele, Qwaqwa Campus, Ms Liesl Hoare, Central Univeristy of Technology, Welkom Campus (best achiever), and Dr Fanus van Tonder, Programme Director: Higher Education Studies and Research, CHESD. Ms Hoare received the Deans medal in the Faculty of the Humanities as the best master’s graduate student at the graduation ceremony. At the faculty’s prize function she also received the Kovsie-Alumni Trust award as the best M.A student in the faculty. She also received the CHESD Prize for the best achievement in the Structured M.A. (Higher Education Studies).
Photo: Leonie Bolleurs

UFS awards degrees at autumn graduation ceremony
Five hundred and eighty six degrees and nine doctorates were awarded this week during this year's autumn graduation ceremony on the South Campus of the University of the Free State (UFS) to students in the Faculty of the Humanities. At the occasion were, from the left: Nicola Bekker, Madré van der Merwe and Esté Scholtz. All three the ladies received the qualification B.A. Language Practice.
Photo: Lacea Loader

This year’s autumn graduation ceremony of the University of the Free State (UFS) is held on the South Campus in Bloemfontein. Today a group of students from the Programme: Governance and Political Transformation in the Faculty of the Humanities received their qualification. From the left, front are: Dr Tania Coetzee, Head of the Programme: Governance and Political Transformation, and Mr Itumeleng Liba, Chief Operation Officer at CENTLEC; back: Mr Kennett Sinclair, Vice-Chairperson of COPE in the Northern Cape, Ms Nicole Joannou, Goldfields Business and Catering, and Mr Tembeni Lobe from Bloemfontein.
Photo: Lacea Loader

Some of the students who received their qualifications during this week's graduation ceremony of the Faculty of the Humanities were, from the left: Shu-Jung Chan, B.Mus. Hons., Brian Gxavu, B.Mus., and Mpolokeng Lepote, B.A. Media Studies.
Photo: Lacea Loader

UFS’s CHESD awards doctoral degree
Ms Mardi Delport (middle), Assistant Director: Media and Communications at the Central University of Technology received her Doctoral degree at this year’s autumn graduation ceremony of the University of the Free State (UFS). The title of her thesis is: “An internal communication model for the Central University of Technology, Free State as a multi-campus institution”. With her are her promoter Prof. Driekie Hay (left), Vice-Rector: Academic Planning, and her co-promoter, Prof. Annette Wilkinson (right) from the Centre for Higher Education Studies and Development (CHESD) at the UFS.
Photo: Leonie Bolleurs

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